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Generation and transformation of a hemi-iminal-based metal–organic Fe(II) structure obtained via subcomponent self-assembly in water

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Abstract

We report the synthesis and characterization of a coordination architecture with a Fe(II) center obtained by subcomponent self-assembly in water. The complex is based on very rare hemi-iminal ligands spontaneously generated from commercially available materials. The complex can be further transformed into another species by oxidation reaction of both the metal center and organic ligand.

Graphical abstract: Generation and transformation of a hemi-iminal-based metal–organic Fe(ii) structure obtained via subcomponent self-assembly in water

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Publication details

The article was received on 28 Aug 2017, accepted on 09 Oct 2017 and first published on 09 Oct 2017


Article type: Paper
DOI: 10.1039/C7DT03182C
Citation: Dalton Trans., 2017, Advance Article
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    Generation and transformation of a hemi-iminal-based metal–organic Fe(II) structure obtained via subcomponent self-assembly in water

    G. Markiewicz, M. Piechocki, A. Walczak, E. A. Połomska, J. Harrowfield and A. R. Stefankiewicz, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03182C

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