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Gate-Opening upon CO2 Adsorption on a Metal-Organic Framework That Mimics a Natural Stimuli-Response System

Abstract

A dynamic metal-organic framework that consists of D-champhorate-based homochiral protuberant-grid-type networks, which can successively participate in gate-opening and closing processes for many cycles, were triggered by the stimuli of the adsorption and desorption of CO2 to highly and specifically recognize CO2 over than N2 and H2 with a high CO2 uptake of 90 mg/g under 35 bar at 298 K. It is highly thermally stable and the structure remains intact at least for ten reversible gate-opening and -closing processes. Thus, it is a potential candidate for industrial CO2 capture and facile release.

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Publication details

The article was received on 22 Aug 2017, accepted on 11 Sep 2017 and first published on 13 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT03119J
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Gate-Opening upon CO2 Adsorption on a Metal-Organic Framework That Mimics a Natural Stimuli-Response System

    T. Tseng, L. Lee, T. Luo, P. Chien, C. Wang, Y. Liu, S. Lee and L. Kuang-Lieh, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT03119J

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