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Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

Abstract

AN OVERVIEW IS GIVEN OF RECENT STRUCTURAL STUDIES ON HETEROMETALLIC URANYL-CONTAINING SPECIES, WITH PARTICULAR EMPHASIS ON THOSE FORMED WITH CARBOXYLATE LIGANDS, SHOWING THE EFFECT OF THE ADDITIONAL METAL CATIONS AND ANCILLARY LIGANDS ON THE GEOMETRY AND TOPOLOGY OF THE ASSEMBLIES GENERATED. THESE EXAMPLES ILLUSTRATE THE SOPHISTICATION WHICH IS NOW POSSIBLE IN THE DESIGN AND SYNTHESIS OF BOTH URANYL CLUSTERS AND COORDINATION POLYMERS.

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Publication details

The article was received on 21 Aug 2017, accepted on 13 Sep 2017 and first published on 14 Sep 2017


Article type: Frontier
DOI: 10.1039/C7DT03105J
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

    P. Thuéry and J. Harrowfield, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT03105J

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