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Issue 36, 2017
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Ring expansion of a ring expanded carbene

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Abstract

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si–H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si–H or Si–Ph bonds.

Graphical abstract: Ring expansion of a ring expanded carbene

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Publication details

The article was received on 16 Aug 2017, accepted on 21 Aug 2017 and first published on 21 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT03046K
Citation: Dalton Trans., 2017,46, 12015-12018
  • Open access: Creative Commons BY license
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    Ring expansion of a ring expanded carbene

    L. García, K. H. M. Al Furaiji, D. J. D. Wilson, J. L. Dutton, M. S. Hill and M. F. Mahon, Dalton Trans., 2017, 46, 12015
    DOI: 10.1039/C7DT03046K

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