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Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

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Abstract

The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P4N2 is preorganized for the dicopper complex formation with the unique coordination mode in the row of P4N2 corands.

Graphical abstract: Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

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Publication details

The article was received on 13 Jul 2017, accepted on 21 Aug 2017 and first published on 01 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT03010J
Citation: Dalton Trans., 2017, Advance Article
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    Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

    T. I. Wittmann, E. I. Musina, D. B. Krivolapov, I. A. Litvinov, S. A. Kondrashova, Sh. K. Latypov, A. A. Karasik and O. G. Sinyashin, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03010J

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