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Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

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Abstract

By employing a nanosized tris(4′-carboxybiphenyl)amine ligand to assemble with Zn2+ ions, a novel trilayer network (FIR-37) and an unprecedented 2D → 3D microporous polycatenation framework (FIR-38) based on unusual tetralayers have been synthesized and structurally characterized. FIR-38 shows permanent porosity with a Langmuir surface area of 1408.4 m2 g−1.

Graphical abstract: Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

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Publication details

The article was received on 11 Aug 2017, accepted on 10 Sep 2017 and first published on 11 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02976D
Citation: Dalton Trans., 2017, Advance Article
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    Polycatenation tuned microporosity of two metal–tris(4′-carboxybiphenyl)amine frameworks with multilayer structures

    Y. He, L. Yuan and J. Zhang, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02976D

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