Jump to main content
Jump to site search


Dinuclear zinc(II) pyrazolates with different degrees of ring-fluorination and their use in zinc(II) mediated olefin aziridination

Author affiliations

Abstract

Zinc complexes [{(3,5-(CF3)2Pz)ZnEt}2(μ-THF)] (1), [{(3-(CF3),5-(t-Bu)Pz)ZnEt}2(μ-THF)] (2), and [{(3,5-(i-Pr)2Pz)ZnEt}2(μ-THF)] (3) adopt dinuclear structures with zinc sites bridged by a THF molecule and two pyrazolate ligands. The zinc complex 1 that features the weakest donating pyrazolate is the best catalyst among the three for the aziridination of styrene and cis-cyclooctene with PhI[double bond, length as m-dash]NTs.

Graphical abstract: Dinuclear zinc(ii) pyrazolates with different degrees of ring-fluorination and their use in zinc(ii) mediated olefin aziridination

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Aug 2017, accepted on 11 Sep 2017 and first published on 12 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02951A
Citation: Dalton Trans., 2017, Advance Article
  •   Request permissions

    Dinuclear zinc(II) pyrazolates with different degrees of ring-fluorination and their use in zinc(II) mediated olefin aziridination

    T. T. Ponduru and H. V. R. Dias, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02951A

Search articles by author

Spotlight

Advertisements