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Issue 37, 2017
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Synthesis, stability and Li-ion mobility of nanoconfined Li2B12H12

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Abstract

This communication presents the first synthesis of nanoconfined Lithium closo-borate, Li2B12H12, using nanoporous SiO2 as scaffold. The yield of Li2B12H12 is up to 94 mol%. The as-synthesized nanoconfined Li2B12H12 exhibits a structural transition around 380 °C and conversion to H-deficiency Li2B12H12−x at 580 °C.

Graphical abstract: Synthesis, stability and Li-ion mobility of nanoconfined Li2B12H12

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Publication details

The article was received on 09 Aug 2017, accepted on 06 Sep 2017 and first published on 06 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02946B
Citation: Dalton Trans., 2017,46, 12434-12437
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    Synthesis, stability and Li-ion mobility of nanoconfined Li2B12H12

    Y. Yan, D. Rentsch, C. Battaglia and A. Remhof, Dalton Trans., 2017, 46, 12434
    DOI: 10.1039/C7DT02946B

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