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A new Mo(IV) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

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Abstract

A heptacoordinate complex [MoIV(DAPBH)Cl2] (H2DAPBH is 1,1′-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)dibenzohydrazine) has been synthesized and characterized structurally and magnetically. It exhibits a slightly distorted pentagonal bipyramidal geometry and reveals paramagnetic behaviour resulting from two unpaired electrons (S = 1) with large positive zero-field splitting (D = +50 cm−1) and pronounced temperature-independent paramagnetism.

Graphical abstract: A new Mo(iv) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

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Publication details

The article was received on 07 Aug 2017, accepted on 14 Sep 2017 and first published on 18 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02912H
Citation: Dalton Trans., 2017, Advance Article
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    A new Mo(IV) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

    V. S. Mironov, T. A. Bazhenova, Yu. V. Manakin, K. A. Lyssenko, A. D. Talantsev and E. B. Yagubskii, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02912H

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