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Slow magnetic relaxation in luminescent mononuclear dysprosium(III) and erbium(III) pentanitrate complexes with the same LnO10 coordination geometry

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Abstract

Two isostructural mononuclear Dy and Er pentanitrate complexes with an LnO10 coordination geometry have been synthesized and studied by single-crystal X-ray diffraction, luminescence and magnetic measurements. Slow relaxation of the magnetization behavior is simultaneously observed in two complexes with the same coordination environment, despite the different types of the 4f-shell electron distribution. Meanwhile, both complexes exhibit the respective characteristic Ln(III) photoluminescence.

Graphical abstract: Slow magnetic relaxation in luminescent mononuclear dysprosium(iii) and erbium(iii) pentanitrate complexes with the same LnO10 coordination geometry

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Publication details

The article was received on 07 Aug 2017, accepted on 16 Oct 2017 and first published on 17 Oct 2017


Article type: Paper
DOI: 10.1039/C7DT02905E
Citation: Dalton Trans., 2017, Advance Article
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    Slow magnetic relaxation in luminescent mononuclear dysprosium(III) and erbium(III) pentanitrate complexes with the same LnO10 coordination geometry

    L. Chen, J. Zhou, A. Yuan and Y. Song, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02905E

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