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Issue 40, 2017
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Synthetic [NiFe] models with a fluxional CO ligand

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Abstract

A [NiFe] complex [(dppe)Ni(pdt)FeCp*(CO)]+ was isolated and characterized as two isomers [1(CO)]+ and [1′(CO)]+. Heating the solution of [1(CO)]+ allowed it to convert into [1′(CO)]+. The one-electron oxidation of [1′(CO)]+ to [1′(CO)]2+ induced fluxional CO movement providing [1(CO)]2+. Recovery of [1(CO)]+ was realized by the one-electron reduction of [1(CO)]2+.

Graphical abstract: Synthetic [NiFe] models with a fluxional CO ligand

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Publication details

The article was received on 06 Aug 2017, accepted on 15 Sep 2017 and first published on 15 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02892J
Citation: Dalton Trans., 2017,46, 13681-13685
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    Synthetic [NiFe] models with a fluxional CO ligand

    X. Chu, X. Yu, S. Raje, R. Angamuthu, J. Ma, C. Tung and W. Wang, Dalton Trans., 2017, 46, 13681
    DOI: 10.1039/C7DT02892J

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