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Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(II) clusters

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Abstract

A novel three-dimensional metal–organic framework [Ni3(BTC)2(bpp)2(H2O)]·3H2O (1) based on mixed ligands H3BTC (1,2,4-benzenetricarboxylic acid) and bpp (1,3-bis(4-pyridyl)propane) was obtained under hydrothermal conditions. Crystal structure analysis reveals that 1 is a framework based on cage-like Ni8(COO)12 units. Furthermore, long-range magnetic ordering is observed at low temperature.

Graphical abstract: Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(ii) clusters

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Publication details

The article was received on 05 Aug 2017, accepted on 06 Sep 2017 and first published on 06 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02889J
Citation: Dalton Trans., 2017, Advance Article
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    Long-range magnetic ordering in a metal–organic framework based on octanuclear nickel(II) clusters

    J. Wang, Y. Bai, H. Pan, G. Zheng and D. Dang, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02889J

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