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Issue 40, 2017
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Fe(II)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization

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Abstract

Fe(II)-Coordinating peptides, having three bidentate 2-(1,2,3-triazol-4-yl)pyridine moieties at their side-chains, were designed based on the naturally occurring siderophore structures. The C3-symmetric macrocyclic peptide and an open-chain congener with the same sequence formed Fe(II)–peptide complexes with opposite metal-centred chiralities.

Graphical abstract: Fe(ii)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization

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Publication details

The article was received on 27 Jul 2017, accepted on 11 Sep 2017 and first published on 12 Sep 2017


Article type: Communication
DOI: 10.1039/C7DT02739G
Citation: Dalton Trans., 2017,46, 13673-13676
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    Fe(II)-Complexation of tripodal hexapeptide ligands with three bidentate triazolylpyridines: induction of metal-centred chirality by peptide macrocyclization

    Y. Kobayashi, T. Kameda, M. Hoshino, N. Fujii, H. Ohno and S. Oishi, Dalton Trans., 2017, 46, 13673
    DOI: 10.1039/C7DT02739G

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