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Issue 37, 2017
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Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

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Abstract

Magnetic f–π interactions between localized 4f-electrons and itinerant π-electrons have been observed in a single crystal of bisphthalocyaninato yttrium(III)/terbium(III) tetrafluoroborate ([Pc2Y0.95Tb0.05][BF4]) by measuring electrical conductivity of the crystal in the presence of an external magnetic field.

Graphical abstract: Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

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Publication details

The article was received on 21 Jul 2017, accepted on 21 Aug 2017 and first published on 21 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT02656K
Citation: Dalton Trans., 2017,46, 12421-12424
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    Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

    T. Fukuda, S. Onodera, H. Watanabe, K. Shirasaki, A. Fuyuhiro, T. Yamamura and N. Ishikawa, Dalton Trans., 2017, 46, 12421
    DOI: 10.1039/C7DT02656K

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