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Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

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Abstract

Magnetic f–π interactions between localized 4f-electrons and itinerant π-electrons have been observed in a single crystal of bisphthalocyaninato yttrium(III)/terbium(III) tetrafluoroborate ([Pc2Y0.95Tb0.05][BF4]) by measuring electrical conductivity of the crystal in the presence of an external magnetic field.

Graphical abstract: Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

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Publication details

The article was received on 21 Jul 2017, accepted on 21 Aug 2017 and first published on 21 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT02656K
Citation: Dalton Trans., 2017, Advance Article
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    Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

    T. Fukuda, S. Onodera, H. Watanabe, K. Shirasaki, A. Fuyuhiro, T. Yamamura and N. Ishikawa, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02656K

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