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Imidazolium cation transportation in a 1-D coordination polymer

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Abstract

We synthesized a coordination polymer, [EtMeIm][Cu(bpy)(Me2PO4)3], containing an anionic 1-D chain and an ethyl methyl imidazolium cation. The organic cations show fast transport behavior, and the observed ion conductivity is 1.4 × 10−3 S cm−1 at 110 °C. The stability and structure of the material were confirmed by DSC, X-ray adsorption, and long-term AC impedance spectroscopy.

Graphical abstract: Imidazolium cation transportation in a 1-D coordination polymer

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Publication details

The article was received on 19 Jul 2017, accepted on 25 Jul 2017 and first published on 25 Jul 2017


Article type: Communication
DOI: 10.1039/C7DT02625K
Citation: Dalton Trans., 2017, Advance Article
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    Imidazolium cation transportation in a 1-D coordination polymer

    W. Chen, N. Ogiwara, K. Kadota, K. Panyarat, S. Kitagawa and S. Horike, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02625K

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