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Issue 37, 2017
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A new family of clusters containing a silver-centered tetracapped [Ag@Ag43-P)4] tetrahedron, inscribed within a N12 icosahedron

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Abstract

An unprecedented silver-centered P-tetracapped [Ag@Ag43-P)4] tetrahedron inscribed within a N12 icosahedral cage has been discovered in the novel family of luminescent clusters. The latter are easily self-assembled by reacting AgI salts with tris(2-pyridyl)phosphine (Py3P).

Graphical abstract: A new family of clusters containing a silver-centered tetracapped [Ag@Ag4(μ3-P)4] tetrahedron, inscribed within a N12 icosahedron

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Publication details

The article was received on 17 Jul 2017, accepted on 23 Aug 2017 and first published on 24 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT02597A
Citation: Dalton Trans., 2017,46, 12425-12429
  • Open access: Creative Commons BY license
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    A new family of clusters containing a silver-centered tetracapped [Ag@Ag43-P)4] tetrahedron, inscribed within a N12 icosahedron

    A. V. Artem'ev, I. Yu. Bagryanskaya, E. P. Doronina, P. M. Tolstoy, A. L. Gushchin, M. I. Rakhmanova, A. Yu. Ivanov and A. O. Suturina, Dalton Trans., 2017, 46, 12425
    DOI: 10.1039/C7DT02597A

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