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Construction of luminescent high-nuclearity Zn–Ln rectangular nanoclusters with flexible long-chain Schiff base ligands

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Abstract

Three Zn–Ln clusters [Ln8Zn6(L1)2(OAc)20(O)2(NO3)4(OH)4] (Ln = Sm (1) and Nd (2)) and [Nd4Zn4(L2)2(OAc)10(NO3)2(OH)4] (3) were prepared using two long-chain Schiff base ligands. The Zn–Ln clusters exhibit interesting nano-square-like structures. Their visible and NIR luminescence properties were investigated.

Graphical abstract: Construction of luminescent high-nuclearity Zn–Ln rectangular nanoclusters with flexible long-chain Schiff base ligands

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Publication details

The article was received on 15 Jul 2017, accepted on 20 Nov 2017 and first published on 20 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT02576A
Citation: Dalton Trans., 2018, Advance Article
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    Construction of luminescent high-nuclearity Zn–Ln rectangular nanoclusters with flexible long-chain Schiff base ligands

    S. Wang, X. Yang, T. Zhu, L. Bo, R. Wang, S. Huang, C. Wang, D. Jiang, H. Chen and R. A. Jones, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT02576A

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