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Preparation of monopodal and bipodal aluminum surface species by selective protonolysis of highly reactive [AlH3(NMe2Et)] on silica

Abstract

The synthesis and the characterization of silica-grafted monopodal and bipodal aluminum hydrides has been achieved starting from 200 °C- and 700 °C-annealed silica and [AlH3(NMe2Et)]. The mechanism by which aluminum trishydride reacts with isolated and vicinal silanols, assisted by the amine, has been investigated computationnally at the ωB97XD-DFT level.

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Publication details

The article was received on 15 Jul 2017, accepted on 09 Aug 2017 and first published on 09 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT02575K
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Preparation of monopodal and bipodal aluminum surface species by selective protonolysis of highly reactive [AlH3(NMe2Et)] on silica

    D. W. Sauter, V. Chiari, N. Aykac, S. Bouaouli, L. Perrin, L. Delevoye, R. Gauvin, K. C. Szeto, M. Taoufik and C. Boisson, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT02575K

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