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Issue 36, 2017
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Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex

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Abstract

2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(III) complex under mild conditions, where the selective metal coordination of the imino group effectively promotes tautomerization of the oxime esters into the N-oxyenamines and the subsequent rearrangement.

Graphical abstract: Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex

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Publication details

The article was received on 12 Jul 2017, accepted on 24 Aug 2017 and first published on 24 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT02528A
Citation: Dalton Trans., 2017,46, 12032-12035
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    Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex

    H. Takahashi, S. Kodama and Y. Ishii, Dalton Trans., 2017, 46, 12032
    DOI: 10.1039/C7DT02528A

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