Issue 36, 2017

Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex

Abstract

2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(III) complex under mild conditions, where the selective metal coordination of the imino group effectively promotes tautomerization of the oxime esters into the N-oxyenamines and the subsequent rearrangement.

Graphical abstract: Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(iii) complex

Supplementary files

Article information

Article type
Communication
Submitted
12 Jul 2017
Accepted
24 Aug 2017
First published
24 Aug 2017

Dalton Trans., 2017,46, 12032-12035

Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex

H. Takahashi, S. Kodama and Y. Ishii, Dalton Trans., 2017, 46, 12032 DOI: 10.1039/C7DT02528A

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