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Issue 36, 2017
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Superior lithium-ion insertion/extraction properties of a novel LiFePO4/C/graphene material used as a cathode in aqueous solution

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Abstract

Herein, olivine LiFePO4 covered with graphene and carbon layers is prepared via a sol–gel method, followed by calcination, and the resultant composite is used as a cathode material in aqueous rechargeable lithium-ion batteries (ARLBs). The phase structure and morphology of the composite are characterized via X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and specific surface area analysis (BET). The ARLB system is fabricated using LiFePO4/C/graphene as the cathode and a zinc anode in 1 mol L−1 ZnSO4·7H2O and saturated LiNO3 aqueous solution without dissolved oxygen, which delivers a capacity of 153 mA h g−1 at 0.5C rate. Even at a 50C rate, it maintains a capacity of 95 mA h g−1 after 200 cycles. The excellent rate capabilities show that this cathode material exhibits good electrochemical performance and this novel ARLB has great potential in the fields of energy storage and high power sources.

Graphical abstract: Superior lithium-ion insertion/extraction properties of a novel LiFePO4/C/graphene material used as a cathode in aqueous solution

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Publication details

The article was received on 28 Jun 2017, accepted on 14 Aug 2017 and first published on 14 Aug 2017


Article type: Communication
DOI: 10.1039/C7DT02341C
Citation: Dalton Trans., 2017,46, 12019-12026
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    Superior lithium-ion insertion/extraction properties of a novel LiFePO4/C/graphene material used as a cathode in aqueous solution

    W. Duan, M. Zhao, J. Shen, S. Zhao and X. Song, Dalton Trans., 2017, 46, 12019
    DOI: 10.1039/C7DT02341C

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