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Issue 30, 2017
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Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates

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Abstract

The synthesis, crystallographic analysis and full characterization of the Cu(I) complex-functionalized Anderson polyoxomolybdate anions (nBu4N)[MMo6O18((OCH2)3CNCH(C47H37N2P2OCu)2)] (M = Mn3+, Fe3+, Co3+) is reported. For the first time, direct crystallographic evidence for the covalent attachment of a photoactive metal complex to an organo-functionalized polyoxometalate is obtained. Initial electrochemical and photochemical studies report fundamental properties and solution stability of the compounds.

Graphical abstract: Structural and reactivity insights into covalently linked Cu(i) complex-Anderson polyoxometalates

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Publication details

The article was received on 26 Jun 2017, accepted on 07 Jul 2017 and first published on 10 Jul 2017


Article type: Communication
DOI: 10.1039/C7DT02316B
Citation: Dalton Trans., 2017,46, 9760-9764
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    Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates

    S. Schönweiz, D. Sorsche, B. Schwarz, S. Rau and C. Streb, Dalton Trans., 2017, 46, 9760
    DOI: 10.1039/C7DT02316B

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