Jump to main content
Jump to site search


Unprecedented ferromagnetic Gd⋯nitronyl nitroxide coupling through a hydrogen bonding bridge

Author affiliations

Abstract

A novel lanthanide(III)–nitronyl nitroxide chain {[Gd(hfac)3(Nit-Ph-3,5-bIm)(H2O)]·C4H10O}n (1) was prepared and characterized. Strikingly, an unexpected ferromagnetic coupling between the Gd(III) ion and the nitroxide group mediated by hydrogen bonding has been observed for the first time.

Graphical abstract: Unprecedented ferromagnetic Gd⋯nitronyl nitroxide coupling through a hydrogen bonding bridge

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Jun 2017, accepted on 11 Jul 2017 and first published on 11 Jul 2017


Article type: Communication
DOI: 10.1039/C7DT02232H
Citation: Dalton Trans., 2017, Advance Article
  •   Request permissions

    Unprecedented ferromagnetic Gd⋯nitronyl nitroxide coupling through a hydrogen bonding bridge

    J. Sun, M. Yang, Z. Sun, X. Wang, Y. Ma and L. Li, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02232H

Search articles by author

Spotlight

Advertisements