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Issue 34, 2017
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A metalloporphyrin-based porous organic polymer as an efficient catalyst for the catalytic oxidation of olefins and arylalkanes

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Abstract

A metalloporphyrin-based porous organic polymer, Mn-PPOP-1, was constructed in high yield via the ketoenamine condensation of robust porphyrin tetraamines (TBPP) with 1,3,5-triformylphloroglucinol. The stable keto-enamine form in the synthesized polymer was unambiguously confirmed by 13C CP-MAS solid state NMR. Noticeably, besides the high thermal and chemical stability, this material contains both micropores and mesopores, which are favorable for mass transfer in the catalytic application. Mn-PPOP-1 exhibits significantly high catalytic oxidation of olefins and arylalkanes at room temperature. The catalytic activity and stability of Mn-PPOP-1 are apparently superior to those of the homogeneous manganese porphyrins. These results indicate that the metalloporphyrin-based porous organic polymer is a promising candidate for efficient heterogeneous catalysts.

Graphical abstract: A metalloporphyrin-based porous organic polymer as an efficient catalyst for the catalytic oxidation of olefins and arylalkanes

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Publication details

The article was received on 13 Jun 2017, accepted on 02 Aug 2017 and first published on 03 Aug 2017


Article type: Paper
DOI: 10.1039/C7DT02149F
Citation: Dalton Trans., 2017,46, 11372-11379
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    A metalloporphyrin-based porous organic polymer as an efficient catalyst for the catalytic oxidation of olefins and arylalkanes

    Z. Ding, W. Zhu, T. Li, R. Shen, Y. Li, Z. Li, X. Ren and Z. Gu, Dalton Trans., 2017, 46, 11372
    DOI: 10.1039/C7DT02149F

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