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A mononuclear Co(II) complex formed from pyridinedimethanol with manifold slow relaxation channels

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Abstract

A mononuclear hexacoordinate complex [Co(pydm)2](dnbz)2 formed from 2,6-pyridinedimethanol in the coordination sphere of Co(II) and dinitrobenzoato anions exhibits magnetic anisotropy of an easy axis type and a field induced slow magnetic relaxation with manifold relaxation channels. The low-frequency relaxation time is as slow as τLF = 0.13 s at BDC = 0.4 T and T = 1.9 K.

Graphical abstract: A mononuclear Co(ii) complex formed from pyridinedimethanol with manifold slow relaxation channels

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Publication details

The article was received on 12 Jun 2017, accepted on 20 Jul 2017 and first published on 20 Jul 2017


Article type: Paper
DOI: 10.1039/C7DT02131C
Citation: Dalton Trans., 2017, Advance Article
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    A mononuclear Co(II) complex formed from pyridinedimethanol with manifold slow relaxation channels

    D. Valigura, C. Rajnák, J. Moncol, J. Titiš and R. Boča, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02131C

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