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Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: synthesis and applications

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Abstract

Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(IV) complexes of the type Cp*2Th(L)(CH3). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.

Graphical abstract: Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: synthesis and applications

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Publication details

The article was received on 11 Jun 2017, accepted on 27 Jun 2017 and first published on 27 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT02126G
Citation: Dalton Trans., 2017, Advance Article
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    Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: synthesis and applications

    T. Ghatak, S. Drucker, N. Fridman and M. S. Eisen, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT02126G

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