Jump to main content
Jump to site search

Issue 43, 2017
Previous Article Next Article

Carbon-sulphur cross coupling reactions catalyzed by nickel-based coordination polymers based on metalloligands

Author affiliations

Abstract

This work illustrates two Ni2+ based coordination polymers (CPs, 1-Ni and 2-Ni) synthesized using two related Co3+ based metalloligands offering appended arylcarboxylate groups. The crystal structure of 1-Ni displays a porous 3D network having well-defined major and minor pores whereas 2-Ni exhibits a somewhat densely packed structure. Both CPs supported the exchange of coordinated water molecules and the inclusion of iodine within their porous structure whereas binding studies illustrated that the Ni(II) ion in these CPs can bind thiophenol, a reagent used in the C–S cross coupling reactions. The two CPs functioned as the reusable heterogeneous catalysts for the C–S cross coupling reactions between substituted aromatic halides and thiophenol as well as cyclohexanethiol and ethanethiol.

Graphical abstract: Carbon-sulphur cross coupling reactions catalyzed by nickel-based coordination polymers based on metalloligands

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Jun 2017, accepted on 04 Oct 2017 and first published on 04 Oct 2017


Article type: Paper
DOI: 10.1039/C7DT02064C
Citation: Dalton Trans., 2017,46, 15023-15031
  •   Request permissions

    Carbon-sulphur cross coupling reactions catalyzed by nickel-based coordination polymers based on metalloligands

    G. Kumar, F. Hussain and R. Gupta, Dalton Trans., 2017, 46, 15023
    DOI: 10.1039/C7DT02064C

Search articles by author

Spotlight

Advertisements