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A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

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Abstract

The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium–uranium and rare heterobimetallic uranium–cobalt and uranium–nickel complexes supported by a redox-active dinucleating ligand.

Graphical abstract: A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

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Publication details

The article was received on 01 Jun 2017, accepted on 08 Jun 2017 and first published on 26 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01993A
Citation: Dalton Trans., 2017, Advance Article
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    A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

    C. Camp, D. Toniolo, J. Andrez, J. Pécaut and M. Mazzanti, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01993A

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