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UV-induced single-crystal-to-single-crystal conversion from a coordination ladder to a two-dimensional network through an intermolecular carbon–carbon coupling reaction

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Abstract

UV irradiation of a ladder-like coordination polymer induces a stereospecific [2 + 2] photocycloaddition reaction of each pair of adjacent olefinic ligands from neighboring coordination ladders and thus affords a unique two-dimensional coordination network in a single-crystal-to-single-crystal manner. The conversion exhibits photocontrolled fluorescence.

Graphical abstract: UV-induced single-crystal-to-single-crystal conversion from a coordination ladder to a two-dimensional network through an intermolecular carbon–carbon coupling reaction

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Publication details

The article was received on 01 Jun 2017, accepted on 30 Jun 2017 and first published on 30 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01989K
Citation: Dalton Trans., 2017, Advance Article
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    UV-induced single-crystal-to-single-crystal conversion from a coordination ladder to a two-dimensional network through an intermolecular carbon–carbon coupling reaction

    J. Chen, Y. Hou, Q. Zhou, H. Zhang and D. Liu, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01989K

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