Issue 30, 2017
From the journal:

Dalton Transactions

Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect†

Qingfang Lin,‡ac   Jing Li,‡b   Yayu Dong,a   Guangpeng Zhou,a   You Song ORCID logo b  and  Yan Xu ORCID logo *ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P.R. China
E-mail: yanxu@njtech.edu.cn

b Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China

c Department of Chemistry, Bengbu Medical College, Bengbu 233030, PR China

Abstract

Two lantern-shaped, high-nuclearity 3d–4f clusters {Ln52Ni52}(Ln = Gd and Dy) were synthesized by using iminodiacetic acid (H2IDA) and isonicotinic acid (HIN) as the co-ligand under solvothermal conditions. Magnetic studies show a large magnetocaloric effect (MCE) for the gadolinium analogue.

Graphical abstract: Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

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Article information

DOI
https://doi.org/10.1039/C7DT01978E
Article type
Communication
Submitted
31 May 2017
Accepted
27 Jun 2017
First published
27 Jun 2017

Dalton Trans., 2017,46, 9745-9749

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Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

Q. Lin, J. Li, Y. Dong, G. Zhou, Y. Song and Y. Xu, Dalton Trans., 2017, 46, 9745 DOI: 10.1039/C7DT01978E

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