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Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

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Abstract

Two lantern-shaped, high-nuclearity 3d–4f clusters {Ln52Ni52}(Ln = Gd and Dy) were synthesized by using iminodiacetic acid (H2IDA) and isonicotinic acid (HIN) as the co-ligand under solvothermal conditions. Magnetic studies show a large magnetocaloric effect (MCE) for the gadolinium analogue.

Graphical abstract: Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

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Publication details

The article was received on 31 May 2017, accepted on 27 Jun 2017 and first published on 27 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01978E
Citation: Dalton Trans., 2017, Advance Article
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    Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

    Q. Lin, J. Li, Y. Dong, G. Zhou, Y. Song and Y. Xu, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01978E

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