A [Ce21] keplerate

Angelos B. Canaj; Milosz Siczek; Tadeusz Lis; Mark Murrie; Euan K. Brechin; Constantinos J. Milios

doi:10.1039/C7DT01883E

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A [Ce₂₁] keplerate†

Angelos B. Canaj,

^a Milosz Siczek,^b Tadeusz Lis,^b Mark Murrie,

*^c Euan K. Brechin*^d and Constantinos J. Milios

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Crete, Voutes 71003, Herakleion, Greece
E-mail: komil@uoc.gr

^b Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland

^c WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK
E-mail: Mark.Murrie@glasgow.ac.uk

^d EaStCHEM, School of Chemistry, University of Edinburgh, David Brewster Road, Edinburgh, UK EH9 3FJ, UK
E-mail: E.Brechin@ed.ac.uk

Abstract

The solvothermal reaction between Ce(NO₃)₃·6H₂O, 2-amino-isobutyric acid, 2-hydroxy-1-naphthaldehyde and 2-amino-2-methyl-1,3-propanediol in MeOH, in the presence of base, leads to the formation of a unique [Ce^IV₁₃Ce ^III₈] keplerate cage.

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Article information

DOI: https://doi.org/10.1039/C7DT01883E
Article type: Communication
Submitted: 25 Apr 2017
Accepted: 26 May 2017
First published: 31 May 2017
This article is Open Access

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Dalton Trans., 2017,46, 7677-7680

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A [Ce₂₁] keplerate

A. B. Canaj, M. Siczek, T. Lis, M. Murrie, E. K. Brechin and C. J. Milios, Dalton Trans., 2017, 46, 7677 DOI: 10.1039/C7DT01883E

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Dalton Transactions