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Generation and characterisation of a stable nickel(II)-aminoxyl radical complex

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Abstract

A stable nickel(II)-aminoxyl radical complex was generated by the reaction of a nickel(II) complex supported by a tren ligand (tris(2-aminoethyl)amine) having bulky m-terphenyl substituents (TIPT: 3,5-bis(2,6-diisopropylphenyl)phenyl) and m-CPBA (m-chloroperoxybenzoic acid). The formation mechanism of the nickel(II)-aminoxyl radical complex was examined.

Graphical abstract: Generation and characterisation of a stable nickel(ii)-aminoxyl radical complex

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Publication details

The article was received on 17 May 2017, accepted on 01 Jun 2017 and first published on 01 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01789H
Citation: Dalton Trans., 2017, Advance Article
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    Generation and characterisation of a stable nickel(II)-aminoxyl radical complex

    A. Parrot, Y. Morimoto, S. Paria, H. Sugimoto, N. Fujieda and S. Itoh, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01789H

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