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1,2-Diaza-4-phosphaferrocenes: synthesis, structural characterization, 57Fe Mössbauer spectrum analysis, and DFT calculation

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Abstract

Two 1,2-diaza-4-phosphaferrocenes [(η5-3,5-R2dp)Fe(η5-CpMe5)] (R = tBu (3), Ph (4)) with a single η5 ring containing two nitrogen atoms are prepared. Mössbauer spectroscopic, electrochemical, and density functional theory (DFT) studies have provided a more detailed understanding of the electronic structures and stabilities of these complexes.

Graphical abstract: 1,2-Diaza-4-phosphaferrocenes: synthesis, structural characterization, 57Fe Mössbauer spectrum analysis, and DFT calculation

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Publication details

The article was received on 12 May 2017, accepted on 08 Jun 2017 and first published on 08 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01732D
Citation: Dalton Trans., 2017, Advance Article
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    1,2-Diaza-4-phosphaferrocenes: synthesis, structural characterization, 57Fe Mössbauer spectrum analysis, and DFT calculation

    L. Duan, X. Zhang and W. Zheng, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01732D

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