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SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2] : A DFT investigation and Comparison with CO2 reactivity

Abstract

Recently, it was shown that samarocene oxide [Cp*2Sm-O-SmCp*2] with Cp*=C5Me5 could react with organic and inorganic anhydrides. The reactions of [Cp*2Sm-O-SmCp*2] with SO2 and SO3 are reported using DFT calculations and compared with the reactivity of CO2. These reactions exhibit similar features yielding [Cp*2-Sm-(μ-η1:η2-OSO2)-SmCp*2] similar to [Cp*2-Sm-(μ-η1:η2-OCO2)-SmCp*2] and [Cp*2-Sm-(μ-η2:η2-O2SO2)-SmCp*2] complexes.

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Publication details

The article was accepted on 11 May 2017 and first published on 12 May 2017


Article type: Communication
DOI: 10.1039/C7DT01703K
Citation: Dalton Trans., 2017, Accepted Manuscript
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    SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2] : A DFT investigation and Comparison with CO2 reactivity

    E. Louyriac, P. Roesky and L. Maron, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT01703K

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