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Issue 24, 2017
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SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity

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Abstract

Recently, it was shown that samarocene oxide [Cp*2Sm-O-SmCp*2] with Cp* = C5Me5 could react with organic and inorganic anhydrides. The reactions of [Cp*2Sm-O-SmCp*2] with SO2 and SO3 are reported using DFT calculations and compared with the reactivity of CO2. These reactions exhibit similar features yielding [Cp*2-Sm-(μ–η12-OSO2)-SmCp*2] similar to [Cp*2-Sm-(μ–η12-OCO2)-SmCp*2] and [Cp*2-Sm-(μ–η22-O2SO2)-SmCp*2] complexes.

Graphical abstract: SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity

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Publication details

The article was received on 10 May 2017, accepted on 11 May 2017 and first published on 12 May 2017


Article type: Communication
DOI: 10.1039/C7DT01703K
Citation: Dalton Trans., 2017,46, 7660-7663
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    SO2 and SO3 reactions with [(C5Me5)2Sm-O-Sm(C5Me5)2]: a DFT investigation and comparison with CO2 reactivity

    E. Louyriac, P. W. Roesky and L. Maron, Dalton Trans., 2017, 46, 7660
    DOI: 10.1039/C7DT01703K

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