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Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly

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Abstract

The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and 1H NMR spectra, provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.

Graphical abstract: Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly

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Publication details

The article was received on 05 May 2017, accepted on 10 May 2017 and first published on 10 May 2017


Article type: Communication
DOI: 10.1039/C7DT01635B
Citation: Dalton Trans., 2017, Advance Article
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    Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly

    Y. Sasano, N. Yasuda and H. Maeda, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01635B

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