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Polymorphism of a chiral iron(II) complex: spin-crossover and ferroelectric properties

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Abstract

Two solvent-free polymorphs of a chiral iron(II) complex have been obtained, and their polymorphism dependent spin-crossover and ferroelectric properties have been demonstrated. Polymorph I shows a gradual spin-crossover behavior, whereas polymorph II remains in a high-spin state but shows a typical ferroelectric feature.

Graphical abstract: Polymorphism of a chiral iron(ii) complex: spin-crossover and ferroelectric properties

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Publication details

The article was received on 05 May 2017, accepted on 26 May 2017 and first published on 26 May 2017


Article type: Communication
DOI: 10.1039/C7DT01634D
Citation: Dalton Trans., 2017, Advance Article
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    Polymorphism of a chiral iron(II) complex: spin-crossover and ferroelectric properties

    W. Han, L. Qin, C. Pang, C. Cheng, W. Zhu, Z. Li, Z. Li, X. Ren and Z. Gu, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01634D

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