Jump to main content
Jump to site search

Issue 26, 2017
Previous Article Next Article

The first ReI organometallic complex with an organoimido-polyoxometalate ligand

Author affiliations

Abstract

The spectroscopic, electrochemical and photophysical properties of the first ReI organometallic organoimido-polyoxometalate complex [n-Bu4N][Mo6O18NC6H4-CH2-N3C2H2-Re-phen(CO)3] compared with all fragments are reported. The UV–Vis spectra are analysed using experimental and theoretical tools. In contrast to the reported studies in the literature, our results show that a new more intense band is present in the spectra of the hybrid ligand obscuring the intra-polyanion charge transfer. The electrochemical results show that the strong acceptor character of the polyoxometalate fragment is quenched by the condensation of the phenyl-triazole molecule.

Graphical abstract: The first ReI organometallic complex with an organoimido-polyoxometalate ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 05 May 2017, accepted on 08 Jun 2017 and first published on 08 Jun 2017


Article type: Paper
DOI: 10.1039/C7DT01633F
Citation: Dalton Trans., 2017,46, 8611-8620
  •   Request permissions

    The first ReI organometallic complex with an organoimido-polyoxometalate ligand

    P. Hermosilla-Ibáñez, K. Wrighton-Araneda, G. Prado, V. Paredes-García, N. Pizarro, A. Vega and D. Venegas-Yazigi, Dalton Trans., 2017, 46, 8611
    DOI: 10.1039/C7DT01633F

Search articles by author

Spotlight

Advertisements