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Issue 37, 2017
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From ethylzinc guanidinate to [Zn10O4]-supertetrahedron

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Abstract

The controlled hydrolysis of an ethylzinc guanidinate complex affording an alkylzinc cluster containing a [Zn10O4]12+ supertetrahedron core stabilized by the guanidinate ligands is described. Accompanying investigations on the reactivity of this unprecedented cluster toward alcohols resulted in the formation of a mononuclear zinc alkoxide supported by the guanidinate ligands.

Graphical abstract: From ethylzinc guanidinate to [Zn10O4]-supertetrahedron

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Publication details

The article was received on 03 May 2017, accepted on 14 Jun 2017 and first published on 14 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01619K
Citation: Dalton Trans., 2017,46, 12404-12407
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    From ethylzinc guanidinate to [Zn10O4]-supertetrahedron

    M. K. Leszczyński, I. Justyniak, K. Zelga and J. Lewiński, Dalton Trans., 2017, 46, 12404
    DOI: 10.1039/C7DT01619K

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