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From ethylzinc guanidinate to [Zn10O4]-supertetrahedron

Abstract

The controlled hydrolysis of an ethylzinc guanidinate complex which affords the alkylzinc cluster containing a [Zn10O4]12+ supertetrahedron core stabilized by the guanidinate ligands is described. Accompaning investigations on the reactivity of this unprecedented cluster toward alcohols resulted in the formation of a mononuclear zinc alkoxide supported by the guanidinate ligands.

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Publication details

The article was received on 03 May 2017, accepted on 14 Jun 2017 and first published on 14 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01619K
Citation: Dalton Trans., 2017, Accepted Manuscript
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    From ethylzinc guanidinate to [Zn10O4]-supertetrahedron

    M. K. Leszczyński, I. Justyniak, K. Zelga and J. Lewinski, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT01619K

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