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Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates

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Abstract

Three types of heterometallic bismuth–tungsten oxide nanoclusters were successfully synthesized by the reactions of lacunary silicotungstates (trivacant [A-α-SiW9O34]10− and divacant [γ-SiW10O36]8−) and Bi3+ in organic solvents. Lone pairs on Bi3+ acted as structure-directing groups in these nanoclusters.

Graphical abstract: Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates

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Publication details

The article was received on 01 May 2017, accepted on 11 May 2017 and first published on 11 May 2017


Article type: Communication
DOI: 10.1039/C7DT01587A
Citation: Dalton Trans., 2017, Advance Article
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    Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates

    T. Hanaya, K. Suzuki, R. Sato, K. Yamaguchi and N. Mizuno, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01587A

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