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Issue 30, 2017
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Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature

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Abstract

The chemical reaction of group-14 elements with molecular nitrogen at pressures above 60 GPa successfully leads to the formation of pyrite-type pernitrides. These new crystalline group-14 elemental pernitrides were found to show a bulk modulus higher than the other known group-14 elemental nitrides. Our results offer significant new progress in the solid-state chemistry of nitrides.

Graphical abstract: Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature

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The article was received on 30 Apr 2017, accepted on 29 Jun 2017 and first published on 29 Jun 2017


Article type: Communication
DOI: 10.1039/C7DT01583F
Citation: Dalton Trans., 2017,46, 9750-9754
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    Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature

    K. Niwa, H. Ogasawara and M. Hasegawa, Dalton Trans., 2017, 46, 9750
    DOI: 10.1039/C7DT01583F

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