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Issue 26, 2017
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Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands

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Abstract

A new synthetic approach to tri-substituted trisalkoxy-hexavanadate clusters containing different organic groups was developed in this work. Four mixed-valence or fully reduced POV hybrids were synthesized and structurally characterized, including an amino-containing derivative of hexavanadate, Na2[VIV3VV3O10{NH2C(CH2O)3}3] (1). Furthermore, a novel mixed-valence POV hybrid was prepared via the amidation of 1, indicating that 1 can be used as an excellent building block for the design and synthesis of mixed-valence POV functional materials.

Graphical abstract: Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands

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The article was received on 27 Apr 2017, accepted on 06 Jun 2017 and first published on 09 Jun 2017


Article type: Paper
DOI: 10.1039/C7DT01543G
Citation: Dalton Trans., 2017,46, 8505-8513
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    Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands

    X. Hu, Z. Xiao, B. Huang, X. Hu, M. Cheng, X. Lin, P. Wu and Y. Wei, Dalton Trans., 2017, 46, 8505
    DOI: 10.1039/C7DT01543G

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