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Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex

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Abstract

The reaction of a Cp*Ir(III) phosphoramidate complex with secondary amines gives amine, imine-bound Cp*Ir(III) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in catalytic amine dehydrogenation using related N,O-chelated Cp*Ir(III) pyridonate complexes.

Graphical abstract: Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex

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Publication details

The article was received on 25 Apr 2017, accepted on 31 May 2017 and first published on 01 Jun 2017


Article type: Paper
DOI: 10.1039/C7DT01499F
Citation: Dalton Trans., 2017, Advance Article
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    Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex

    M. W. Drover, L. L. Schafer and J. A. Love, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01499F

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