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Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane

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Abstract

The complex [(PNHP)Fe(H)(CO)(HBH3)] (PNHP = HN(CH2CH2Pi-Pr2)2) serves as a catalyst precursor for the selective dehydrocoupling of methylamine borane at room temperature, tentatively via an off-metal polymerisation pathway.

Graphical abstract: Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane

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Publication details

The article was received on 25 Apr 2017, accepted on 27 Apr 2017 and first published on 27 Apr 2017


Article type: Communication
DOI: 10.1039/C7DT01487B
Citation: Dalton Trans., 2017, Advance Article
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    Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane

    F. Anke, D. Han, M. Klahn, A. Spannenberg and T. Beweries, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01487B

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