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Determination of Zero-Field Splittings in Co2+ Halides Complexes with Magnetic and Far-IR Measurements

Abstract

Three penta-coordinate Co2+ complexes with halides substitutes were synthesized. Their zero-field splitting (ZFS) parameters were determined by fitting dc magnetic data and far-infrared magneto-transmission spectra. The results gave an unusual case that complexes with heavier halide atoms bear smaller ZFS parameters.

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Publication details

The article was received on 25 Apr 2017, accepted on 18 May 2017 and first published on 18 May 2017


Article type: Communication
DOI: 10.1039/C7DT01486D
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Determination of Zero-Field Splittings in Co2+ Halides Complexes with Magnetic and Far-IR Measurements

    J. Liu, Y. Meng, I. Hlavička, M. Orlita, S. Jiang, B. Wang and S. Gao, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT01486D

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