Jump to main content
Jump to site search

Issue 22, 2017
Previous Article Next Article

Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structure

Author affiliations

Abstract

Two fluorophosphates, BaMPO4F (M = Cu, Co), have been synthesized by a conventional hydrothermal method, and they crystallize in the orthorhombic system with the space group P212121, exhibiting a tunnel structure built by distorted MO4F square-pyramids and PO4 tetrahedra. The magnetic behaviors of the two compounds are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. The results indicate that BaCuPO4F exhibits a paramagnetic behavior down to 2 K, while BaCoPO4F undergoes long-range antiferromagnetic ordering at 11.3 K and short-range magnetic ordering at ∼22 K.

Graphical abstract: Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structure

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Apr 2017, accepted on 12 May 2017 and first published on 15 May 2017


Article type: Paper
DOI: 10.1039/C7DT01408B
Citation: Dalton Trans., 2017,46, 7261-7266
  •   Request permissions

    Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structure

    C. Qiu, Z. He, M. Cui and S. Chen, Dalton Trans., 2017, 46, 7261
    DOI: 10.1039/C7DT01408B

Search articles by author

Spotlight

Advertisements