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Issue 22, 2017
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Redox effects of low-spin Ru(II/III) on slow magnetic relaxation of Ru–Mn(III) 1D cyanide-bridged complexes

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Abstract

A new one-dimensional cyanide-bridged complex [MnIII(salphen)RuII(DMAP)4(CN)2](PF6) (1) and its oxidized derivative [MnIII(salphen)RuIII(DMAP)4(CN)2](PF6)2 (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow magnetic relaxation.

Graphical abstract: Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru–Mn(iii) 1D cyanide-bridged complexes

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Publication details

The article was received on 05 Apr 2017, accepted on 06 May 2017 and first published on 08 May 2017


Article type: Paper
DOI: 10.1039/C7DT01218G
Citation: Dalton Trans., 2017,46, 7267-7272
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    Redox effects of low-spin Ru(II/III) on slow magnetic relaxation of Ru–Mn(III) 1D cyanide-bridged complexes

    X. Zhu, S. Su, W. Cao, Y. Wen, S. Hu, X. Wu and T. Sheng, Dalton Trans., 2017, 46, 7267
    DOI: 10.1039/C7DT01218G

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