Jump to main content
Jump to site search


Redox effects of low-spin Ru(II/III) on slow magnetic relaxation of Ru–Mn(III) 1D cyanide-bridged complexes

Author affiliations

Abstract

A new one-dimensional cyanide-bridged complex [MnIII(salphen)RuII(DMAP)4(CN)2](PF6) (1) and its oxidized derivative [MnIII(salphen)RuIII(DMAP)4(CN)2](PF6)2 (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow magnetic relaxation.

Graphical abstract: Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru–Mn(iii) 1D cyanide-bridged complexes

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 05 Apr 2017, accepted on 06 May 2017 and first published on 08 May 2017


Article type: Paper
DOI: 10.1039/C7DT01218G
Citation: Dalton Trans., 2017, Advance Article
  •   Request permissions

    Redox effects of low-spin Ru(II/III) on slow magnetic relaxation of Ru–Mn(III) 1D cyanide-bridged complexes

    X. Zhu, S. Su, W. Cao, Y. Wen, S. Hu, X. Wu and T. Sheng, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01218G

Search articles by author