Jump to main content
Jump to site search

Issue 24, 2017
Previous Article Next Article

Ionic liquid promotes N2 coordination to titanocene(III) monochloride

Author affiliations

Abstract

Coordination of N2 to [(Cp2TiCl)2] in a non-coordinating ionic liquid, Pyr4FAP, was studied by UV-vis/NIR and EPR spectroscopies. [(Cp2TiCl)2] is in equilibrium between monomeric [Cp2TiCl] and dimeric species [(Cp2TiCl)2]. The frozen solution EPR spectrum revealed the coordination of N2 to [Cp2TiCl], suggesting that Pyr4FAP promotes N2 coordination to the Ti(III) center.

Graphical abstract: Ionic liquid promotes N2 coordination to titanocene(iii) monochloride

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Mar 2017, accepted on 12 May 2017 and first published on 23 May 2017


Article type: Communication
DOI: 10.1039/C7DT01063J
Citation: Dalton Trans., 2017,46, 7668-7671
  •   Request permissions

    Ionic liquid promotes N2 coordination to titanocene(III) monochloride

    A. Katayama, T. Inomata, T. Ozawa and H. Masuda, Dalton Trans., 2017, 46, 7668
    DOI: 10.1039/C7DT01063J

Search articles by author

Spotlight

Advertisements