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Issue 18, 2017
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Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate FeIII complex with a N3O3 coordination sphere

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Abstract

A novel neutral heteroleptic FeIII complex from two kinds of π-extended tridentate ligands was designed and prepared. The π-ligands formed a three-dimensional purely π-stacking interaction network. The present complex proved to be the first neutral spin-crossover (SCO) FeIII complex with a N3O3 coordination sphere exhibiting an abrupt SCO transition with a thermal hysteresis of 10 K and the light-induced excited spin-state trapping effect.

Graphical abstract: Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate FeIII complex with a N3O3 coordination sphere

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Publication details

The article was received on 22 Mar 2017, accepted on 27 Mar 2017 and first published on 31 Mar 2017


Article type: Communication
DOI: 10.1039/C7DT01030C
Citation: Dalton Trans., 2017,46, 5786-5789
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    Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate FeIII complex with a N3O3 coordination sphere

    S. Murata, K. Takahashi, T. Mochida, T. Sakurai, H. Ohta, T. Yamamoto and Y. Einaga, Dalton Trans., 2017, 46, 5786
    DOI: 10.1039/C7DT01030C

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