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Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

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Abstract

The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and n-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.

Graphical abstract: Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

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Publication details

The article was received on 21 Mar 2017, accepted on 02 May 2017 and first published on 02 May 2017


Article type: Paper
DOI: 10.1039/C7DT01019B
Citation: Dalton Trans., 2017, Advance Article
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    Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

    J. B. Brazier, M. A. Newton, E. M. Barreiro, L. A. Adrio, L. Naya and K. K. (. Hii, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT01019B

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