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Highlight on the solution processes occurring on silver(I)-assembling porphyrins in the presence of an excess of silver salt

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Abstract

Coordination cages obtained upon complexation of pyridyl functionalized porphyrins by Ag+ disassemble when overtaking a 1 : 2 stoichiometric amount of silver salt. An excess of Ag+ then leads to unusual chemical processes, here analyzed in detail, which permanently transform the monomeric porphyrins. The observed processes, discussed with reference to model compounds devoid of polyether substituted pyridyl residues, evidence a peculiar reactivity for meso 2,6-dimethylphenyl substituted porphyrins.

Graphical abstract: Highlight on the solution processes occurring on silver(i)-assembling porphyrins in the presence of an excess of silver salt

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Publication details

The article was received on 17 Mar 2017, accepted on 21 Jun 2017 and first published on 07 Jul 2017


Article type: Paper
DOI: 10.1039/C7DT00974G
Citation: Dalton Trans., 2017, Advance Article
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    Highlight on the solution processes occurring on silver(I)-assembling porphyrins in the presence of an excess of silver salt

    T. T. Dang, S. Durot, L. Monnereau, V. Heitz, A. Barbieri and B. Ventura, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT00974G

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